Now you’re just playing pathetic word games. 
That which can be asserted without evidence, can be dismissed without evidence
Thus, lacking evidence (after Jull and Freer-Waters conscientious search), the ‘patch’/‘repair’ claim can be unequivocally rejected.
In the same way, I could unequivocally reject the claim that you are an alien lizard-person. 
Has he? Much of the claims he makes in his paper appears to be vague hearsay – neither substantiated by an explicitly cited source, nor by first-hand observation.
Add to that the “home laboratory” environment under which he conducted his experiments, and the unclear provenance of the (apparently purloined) samples he was using, and it hardly rates as “evidence”.
I note you have still failed to engage with Jull and Freer-Waters’ evidence Gil.
Emphasis on the word “may”. Unlike carbon-dating it has not been validated. Also unlike carbon dating, as it relies on chemical, rather than nuclear, reactions, it is vulnerable to environmental factors – meaning that it is inherently less reliable.
This means that the only thing it would appear to have going for it is that it gave Rogers the answer he wanted. It might be appropriate to rename it from “the vanillin test” to “Rogers’ I really really *really want to believe the shroud is authentic test”.
Addendum: on the lack of “confirmation”, the lack of interest in this ‘test’ in the 20-odd years since Rogers’ publication would appear to further indicate that it wasn’t so much a serious method of dating so much as a desperate attempt to manufacture doubt.
Given that neither you nor Bill have presented any evidence supporting this disagreement, I feel no qualms about dismissing it out of hand.
Could it be that your lack of “courage” is due to the fact that they are all so flimsy, unsubstantiated, speculative and/or based on wishful-thinking, that you expect them to be immediately demolished?
How is it “useful”? Does it present hard evidence, or simply parrot a laundry-list of authenticist claims? Who is “Joseph G. Marino” that we should put any trust in his claims? His Amazon bio doesn’t appear to suggest anything even remotely resembling expertise or objectivity:
Joseph Marino has a B.A. in Theological Studies from St. Louis University and is a long-time sindonologist (one who studies the Shroud of Turin). He has researched, written and lectured extensively on the Shroud since 1977. He currently works at The Ohio State University in Columbus, Ohio.
Just yet another credulous, ill-qualified authenticity-fanatic.
Addendum: I tracked Marino down at OSU – he is (or was) apparently a " Library Associate I in Serials/Electronic Resources/Rights Management" rather than an academic, and appears to be mentioned by that institution solely in connection to his shroud efforts.