Paul Giem: Isochron Dating Rocks and Magma Mixing

I do not understand why everything that’s a problem for YECs is not also a problem for YLCs, as long as we’re talking about the Phanerozoic or, probably, Proterozoic.

So how do you resolve these problems while remaining a YLC? Surely it’s impossible to believe that a worldwide flood laid down the Phanerozoic record.

But the earth wasn’t chaotic for 4.6 billion years, was it? If radiometric dating tells you the earth is 4.6 billion years old, how can you discount it when it tells you the Cambrian is 541 million years old?

I’m trying to figure out how you can possibly believe that. Please explain.

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Roy (C77),

RonSewell:
jammycakes:

Especially when you are making extraordinary claims that hundreds of thousands of results taken using dozens of different methods are all consistently out by factors of a million.

PaulGiem:

And dozens of different methods? Really?

From Paul Giem, Scientific Theology , p.116

There are several books on dating methods. Perhaps one of the better ones for an initial survey is *Absolute Dating Methods* by Mebus A. Geyh and Helmut Schleicher.5 This book lists 76 physical and chemical methods used to date the earth, the moon, meteorites, or fragments thereof.

Game, set, match.

You failed to read further in Scientific Theology (pp. 136, 137):

So we turn again to Geyh and Schleicher and look at those 75 other methods [besides K/Ar dating]. Some of them, such as 138La/138Ce, 176Lu/176Ha, and 207Pb/206Pb, are used only for Precambrian material, and thus are irrelevant for dating life. They may be valid, or they may be invalid, but it doesn’t really matter for our purposes. Some, such as 3H, 210Pb, and 228Th excess/232Th, are used only for recent (< 3000 year old) samples, and thus again irrelevant for the question at hand. Some are considered highly experimental, such as the 10Be/36Cl method (if evolutionists do not have confidence in a method or its assumptions, it would seem difficult to use it to disprove a creationist time scale). Some are essentially variations on other methods, such as the 39Ar/40Ar method.41 Some are only relative dating methods, such as paleomagnetism and stable oxygen isotopes. Some are used on only meteorites or lunar rocks and are mostly irrelevant for dating life on the earth (all except for the terrestrial ages of meteorites). And some are obsolete, like the chemical lead method. Some, of course, suffer from more than one drawback for our purposes. When all these extraneous methods are removed from consideration, we are left with the following methods: 87Rb/87Sr, 40K/40Ca, 147Sm/143Nd, uranium/thorium/lead and lead/alpha, krypton/krypton, uranium/xenon and xenon/xenon, 14C, 36Cl, 53Mn, 81Kr, 129I, 26Al, 10Be, most of the U and Th disequilibrium series, U/He, Thermoluminscence and relatives, Fission tracks, Pleochroic haloes, terrestrial exposure ages of meteorites, Amino acid racemization, Nitrogen content of bones, and Obsidian hydration. This is still an impressive list, but a far cry from the 76 methods we started with. And this list can be whittled down still further.

Not quite the “dozens and dozens” mentioned earlier (minimum of 48 by my count) Can I have my point back? Or perhaps better, as swamidass said (C78),

Except this isn’t about scoring points. At least it shouldn’t be :frowning:

About that “Gish Gallop” (jammycakes, C68), there is no way I am going to vet all of the 100 reasons (although they are billed as “the 100 most convincing reasons—in no particular order—that the Earth is not less than 10,000 years old.”). But I may reply to a few.

Tree-ring “long counts” from [California](https://journals.uair.arizona.edu/index.php/radiocarbon/article/view/787), [Central Europe](https://journals.uair.arizona.edu/index.php/radiocarbon/article/view/4172), [New Zealand](http://onlinelibrary.wiley.com/doi/10.1002/jqs.1075/abstract), and [Scandinavia](http://www.tandfonline.com/doi/abs/10.1080/00291950802517593#.VCCb7StdVyE) extend up to ~13,000 years. These chronologies are constructed from hundreds of individual trees that overlap, so that even if a tree *did* produce multiple rings during a growth season, the ‘extra years’ would disappear in the correlation process. Even John Woodmorappe [has written](https://answersingenesis.org/age-of-the-earth/biblical-chronology-and-8000-year-bristlecone-pine-chronology/) that these tree-ring chronologies cannot be explained by multiple rings being produced in a single year or the mismatch of individual tree records.

The matches may not be as secure as assumed (my work on the bones from Nineveh may be relevant here). But even if they are, they only put a putative Flood back past 13,000 years.

There is no radiocarbon in old samples , despite claims to the contrary. Geologically old samples of coal, diamonds, and graphite, for example, yield finite radiocarbon ages that are [consistent with the expected level of contamination](http://www.asa3.org/ASA/education/origins/carbon-kb.htm) invariably introduced during sample collection and preparation.

We’ve been discussing that here, and I may discuss that further in the other thread ( Radiocarbon in Coal? )

Coal beds defy rapid deposition , because the high concentration of organic matter begins with the slow accumulation of plant material in oxygen-poor swamps (and *not* by [rapid burial of floating forests](http://www.oldearth.org/floating.htm)). The occasional preservation of leaves and woody material in coal seams would not be possible if all the buried plant material were fresh to begin with (as with rapid burial of existing forests), but requires that organic remains be at varying stages of decomposition.

The writer is apparently not acquainted with the evidence for the allochthonous origin of coal.

Fossilized poop , called coprolite, is found throughout the fossil record alongside the animals that produced them. These paleontological oddities [are indicative of normal ecological conditions](http://thenaturalhistorian.com/2013/08/10/nh-notes-dino-doo-doo-coprolites-and-the-genesis-flood/) and contradict any scenario in which the ‘poopers’ were catastrophically buried.

How do you fossilize poop without burying it rapidly?

Fossilized tracks in eolian (desert dune) deposits , such as the Coconino and Navajo sandstones, are inconsistent with the young-Earth proposition that these sediments accumulated under water. Extremely high sustained flow rates (>2 m/s) of very deep waters (up to 100 m or more) are required to form dunes of comparable size to those in the Coconino and Navajo sandstones. At these flow rates, it would be impossible for any submerged animals (especially small reptiles) even to make contact with the sediment surface, let alone for any prints to be preserved.

The writer is apparently not acquainted with the work of Leonard Brand showing that the tracks were laid down underwater, published in the standard literature.

Accelerated nuclear decay is science fiction. Neither the physics nor the math produces a result in which radiometric dates yield consistently large ages for rocks and minerals in our solar system. One cannot tweak the physical properties of atoms, so as to increase the rate of radioactive decay, without all hell breaking loose—literally. Rates of decay depend on the stability of individual atoms, so if unstable atoms became more unstable, we’d expect stable atoms also to become very unstable, which would be the undoing of the physical universe as we know it. These are not conditions through which an Ark of humans and animals ever could have survived.

That’s a good argument at present against YEC; YLC, not so much.

swamidass,

It would be nice if the comment numbers were posted on the comments themselves. When i searched, comment 49 on the running total was labeled as comment 50 on the search function.

Not entirely. It seems to me that some of the relative dating methods can still be used to rule out young life. Magnetic reversals, for example, still must have a minimum credible separation of some kind. How many would you seriously believe could happen in a single year?

Of course it is. YLC needs an accelerated decay rate to put the Phanerozoic into a single year. It is a single year, isn’t it? Flood geology?

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Are you SDA? Not meaning to be inquisitorial at all, just curious.

No. No-one mentioned “dozens and dozens” earlier.

Deposit it in a desert where it dries and hardens before being gradually covered by sand.

How do you fossilize poop in a flood?

Alternatively, the writer may have read Leonard Brand’s work and know exactly what is wrong with it.

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I’ve been watching too much Wimbledon.

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Thanks for clearing up that you’re a YLC rather than a YEC. However, you do need to make that crystal clear to everyone from the outset. Otherwise you are just going to end up with other people assuming (as I did) that you hold to a position that you do not.

Well in that case, my first point applies. They will be doing so for two reasons: (a) to narrow down the error range, and (b) to advise the lab of factors such as what kind of sample size to use in order to cut down the number of analysis steps and to save costs. Also, what precisely does the form ask for?

In any case, the lab is first and foremost going to be reporting raw uninterpreted data – raw isotope quantities. Yes, they may plot an isochron and do the calculations afterwards, but they will still need to report the direct measurements from their mass spectrometers. To suggest that they are programming their AMS spectrometers to give them the results that researchers want, rather than results that are based on reality, is (a) an accusation of scientific fraud, (b) a conspiracy theory, and (c) so far fetched as to be ridiculous.

Of course there’s nothing wrong with that. That’s how error bars are determined in every area of science.

No I’m not. I’m just pointing out that you still have to deal with in situ contamination as well as sample processing. And as @RonSewell and others have pointed out, in situ contamination is a well known and well studied problem in coal.

Total contamination, Paul. Total contamination.

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Agreed. The only explanation you are likely to get is their interpretation of Genesis, which allows the Earth (and maybe the universe?) to be much older. I’ll ask the YBC guys to clarify next I get a chance.

He was clear in this thread itself. YBC is fairly common, and it behooves us to ask. It’s common to group them in with YEC, but in these sorts of conversations on the details we shouldn’t make assumptions.

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But why suppose the earth is old? What evidence do they accept that requires such a belief?

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I realize “their interpretation of Genesis” isn’t a very satisfactory answer but it’s all I’ve got just now. Don’t expect to be satisfied even after I can correctly describe their belief. :wink:

They would accept, for example, ancient starlight and radioactive dating (of non fossiliferous strata) as evidence of an ancient earth and universe.

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Ancient starlight is evidence only of an ancient universe, not an ancient earth. And how can you accept radiometric dating of meteorites and Archaean rocks while rejecting dating by identical methods of Phanerozoic rocks? You’re just raising more questions here. Are you even sure you’re in a position to speak for YLCs?

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Found this.

http://creationwiki.org/Young_Biosphere_Creation_(YBC)

This sounds like a good question for @PaulGiem .

I see that there is no discussion of science or any data other than textual analysis of Genesis.

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That doesn’t work for U/Pb concordia/discordia dating. The initial ratio of the two different U isotopes doesn’t matter, and nearly all of the Pb is excluded during zircon formation. One only needs to use isochron methods for very precise dates, but the non-isochron U/Pb dates are still pretty good if I understand the methods correctly (geologists correct me if I am wrong).

Magma mixing can’t explain these results because zircons will have nearly zero Pb when the form no matter how much Pb is in the magma to begin with. Ar boils out of the lava before it solidifies, so it doesn’t matter how much Ar is present in the magma to begin with. And yet, all of these methods agree with one another across different labs and different minerals.

Where is the evidence that the two U/Pb ratios do not agree with one another most of the time? What is the amount of disagreement?

Those were submarine pillow basalts. The solution is not to use them with the K/Ar method. From the paper:

You would still need to explain how this would produce consilience between the other radiometric dating methods.

This is why they don’t use rocks that have xenocrysts in them. Geologists do know which samples are appropriate for dating and which are not.

What’s wrong with the studies that have already been done?

Papers describe the location and strata that the rocks were taken from. Once again, if it is a field wide conspiracy of throwing out dates people don’t like then it is a simple matter of measuring those same rocks. Accusing scientists of fudging their data requires some actual evidence.

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In this article, you raise some avenues of investigation into carbon dating from a creationist perspective.

The Existence of Carbon-14 in Very Old Fossil Material

I do not think there is a lot for me to add further to what has been discussed above; we both agree there is some degree of contamination. I am satisfied that together with inherent limitations of 14C measurement, that explains any trace radiometric carbon; beyond that we are at an impasse at present.

Errors in the Calibration Curve in the Historical Era

It appears to me that 14C dating is applied to validate archaeology much more than the other way around. For one, the earliest specific date which seems to enjoy universal recognition seems to be 690 BC with Sennacherib’s engagement with Hezekiah and Taharqa. Earlier than that and bickering over dates for historic events and figures is a cottage industry. If one cannot find a date to argue over, there is always the Thera eruption. Another limitation is that reuse, repurpose, and recycle was practised by conscientious ancients, so association with a given site does not guarantee an object is of the same age. There has been work on the dead sea scrolls as you mention elsewhere, and 14C dating routinely goes on so the list of artifacts dated piles on up, but I do not think anything too out of line with history has presented itself.

Given that you wrote this in 1997, I am not sure how you would respond to the considerable work done since. Intcal98, Intcal04, Intcal09, Intcal13, and Intcal20, have advanced the art. There is a better understanding of systemic regional offsets due to hemisphere, latitude, growing season, and other local effects. A very significant development from 2012 is the recognition of what stands as the most pronounced cosmogenic event to be captured in the record. This signature from AD 774 is found in dendrochronologies from Japan, North America, Europe, New Zealand, and Russia, providing a sharp synchronization event at a reasonably past distance. Interestingly, to my knowledge no tree ring chronologies had to be modified as a result. Zero missing rings over a millennium serves to validate confidence in the tree ring chronologies, and I am unable to find a creationist response.

Given that you do not seem to be a fan of speeded up decay, and that the tree ring / 14C conscilience is well supported, it appears to me that of the options you lay out in the article, that an ancient flood, constant decay model is the only one consistent with this scope of evidence.

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John_Harshman (C81)

The major difference between YECs and YLCs has to do with the explanation of why the higher concentrations of daughter elements corresponds roughly with the higher concentration of parent isotopes. YECs require accelerated decay, whereas YLCs don’t. There is also starlight, but that is a problem for young universe creationists, not specifically for young earth creationists

Perhaps we can discuss the Flood elsewhere. Right now I prefer not to have this thread any more cluttered than it already is.

But the earth wasn’t chaotic for 4.6 billion years, was it? If radiometric dating tells you the earth is 4.6 billion years old, how can you discount it when it tells you the Cambrian is 541 million years old?

Well, actually, radiometric dating doesn’t tell us that the earth itself is 4.6 billion years old; as I understand it, that date is from meteorites, not the earth itself. It isn’t that I (or others) would say that radiometric dates are all accurate at the beginning, but rather that it helps our model to have time for the aforementioned decay to take place (without vaporizing the earth).

PaulGiem: You can disagree with this interpretation if you want. But I don’t think it is entirely unreasonable.
I’m trying to figure out how you can possibly believe that. Please explain.
I won’t spend a long time explaining, but what I had reference to was not whether the model could be defended scientifically (although I believe that it can), but rather whether it could be defended Biblically. I’m quite aware that you find Flood geology incredible.

(C83)

PaulGiem: That’s a good argument at present against YEC; YLC, not so much.
Of course it is. YLC needs an accelerated decay rate to put the Phanerozoic into a single year. It is a single year, isn’t it? Flood geology?
Maybe, maybe not. Part of the advantage of using mixing lines to interpret apparent isochron lines is that they don’t require accelerated decay.

swamidass (C84),

You nailed it again. Can you teach some of the commentators how to listen carefully? :slight_smile:

Roy (C85),

No. No-one mentioned “dozens and dozens” earlier.
I am sorry. You are right. That was a bad memory slip. What is worse, it was in an uncharitable direction. I stand corrected.

I agree that the list has more than 24 members (“dozens”), although when it is whittled down further, I think it does go below the 24 member limit. And some of them, such as amino acid dating (and IMO 14C dating), give a net argument for a shorter age. But however the dust settles on this question, it does not excuse my mistake.

Does that mean you shouldn’t trust me? Why, yes it does. (I can hear the Amens already :wink: ). Science is supposed to be arranged so that the only true authorities are observation, that is supposed to be reproducible, and logic, which anyone sufficiently intelligent can see. Authorities in science are authoritative precisely because they are transparent. Any hint of non-transparency makes that person less authoritative. (That is probably why science has resisted postmodernism so long; science does not encourage constructing your own truth.)

That’s why I am not upset with you for making me look bad; I am thankful for your correction (except for a tiny part of me that I am choosing to suppress at present :slight_smile: ).

Alternatively, the writer may have read Leonard Brand’s work and know exactly what is wrong with it.
Maybe, but the papers are pretty convincing. Don’t forget that they got published in spite of going against the prevailing (desert) paradigm.

jammycakes (C87),

To suggest that they are programming their AMS spectrometers to give them the results that researchers want, rather than results that are based on reality
is not what I am doing.
Total contamination, Paul. Total contamination.
We’ll discuss that in the “Radiocarbon in Coal?” thread (that is, if they let me).

T_aquaticus,

PaulGiem:

Perhaps the easiest way one can see how the dates could be identical but misleading is to suppose that one starts out with 2 magmas, A and B. One ages them. One then mixes them in various proportions, and obtains “isochron” lines that are actually mixing lines.

That doesn’t work for U/Pb concordia/discordia dating. The initial ratio of the two different U isotopes doesn’t matter, and nearly all of the Pb is excluded during zircon formation.

The initial ratio of the two different U isotopes is always constant, or perhaps better, predictable (it does change with time), except at the Oklo formation (depleted in U-235)—otherwise uranium mines would be rated for their U-235 percentage. That means we reasonably know the initial ratio.

You are making the assumption that zircon formation is at the same time as the last time a given magma was melted, which is probably incorrect, as inherited zircon age is a known problem. Thus, since zircons have an especially high melting point and may still be solid in a magma, a date on a zircon is not necessarily the date the magma was last cooled from a hot slurry. Don’t believe me? just ask N. H. Gale: “The dating of plutonic events.” In Odin GS (ed): Numerical Dating in Stratigraphy. Chinchester, UK: John Wiley and Sons, 1982, pp. 441-50:

Even though, [sic] a zircon suite may be well-dated by the U-Pb discordia method . . . , there can still be doubt whether this date is that of the rock formation itself or whether the zircons are detrital or have inherited radiogenic lead, resulting in the U-Pb result giving an ‘age’ older than the rock formation. (This danger is also inherent in fission track ages of zircons from bentonites.)[pp 446-7]

You say,

Ar boils out of the lava before it solidifies, so it doesn’t matter how much Ar is present in the magma to begin with.

We already know that substantial amounts of argon can be retained if the lava flow is under water. So it is of interest that the Columbia basalt has pillow lava at its edges. And remember that even lava that flows under air retains some argon. It just is sometimes able to be subtracted out because its isotopic composition matches that of modern air argon.

You say,

And yet, all of these methods agree with one another across different labs and different minerals.

I’m looking for blinded tests, with all data reported. Maybe my suspicions are wrong, and I will have to reassess my present position. But every time someone states that we have enough data and shouldn’t try something that in medicine would be absolutely required, my suspicions deepen. Just do the tests.

We’ve covered this before, but I’ll try again. When I read of argon leakage to explain low K/Ar dates, and argon retention to explain high ones, sometimes applied inconsistently (for example, the concern over phenocrysts in lava in Dalrymple 1969, then the rejection of glass dates in favor of phenocryst dates in Maniken and Dalrymple 1972 [“Electron microprobe evaluation of terrestial basalts for whole-rock K-Ar dating.” Earth Planet Sci Lett 17:89-94—In one case the glass in question was unaltered, and still gave a potassium/ argon age of 1.6 million years rather than 7.4 million years]), and knowing that in many rocks we can get 3 or 4 different K/Ar dates (don’t get me started on Ar/Ar dates), and realizing that both high (more often) and negative (much less often) Rb/Sr dates can be obtained and then written off without further proof as mixing lines without anyone asking whether the same could be said for “good” dates, and finally when U/Pb dates (see below) are mostly discordant, I really want concordance with blinded dates before I can feel comfortable accepting radiometric dating at face value. If you’re really that confident that radiometric dating is valid, just do it. If not, maybe I shouldn’t be confident either.

There is one other caveat. It would be best if we select samples that have not yet been dated, both to avoid selecting previously reported matching data, and to avoid previously selected non-matching data. The Cardenas basalt in the Grand Canyon, for example, is known to be non-matching and should not be used.

You say,

Where is the evidence that the two U/Pb ratios do not agree with one another most of the time? What is the amount of disagreement?

It is not often realized that the very fact that U-238/Pb-206 and U-235/Pb-207 ratios are not on the concordia line means that the model dates do not match. If they did, the ratios would plot on the concordia line. That’s what the concordia line means; it is where the dates are concordant. (It is, BTW, not a straight line.)

You ask what the amount of disagreement is. That depends on the specific data. The data in Wikipedia ( https://en.wikipedia.org/wiki/Uranium–lead_dating ) isn’t that far off of the concordia line, just meaning somewhere between 10 and 20 million years discordance(out of some 220 million years) for the lower data point, and the upper data point virtually matches the concordia line. I have seen other data that can differ by close to 50%. (See slide 10 of https://websites.pmc.ucsc.edu/~pkoch/EART_110A/Lectures/L4%20Time&Tectonics.pdf , the lower sample, although this data may be artificial.)

But perhaps more important is the interpretation such data are given. Rather than simply giving 3 dates with, say, 220, 410, and 455 Ma, what is done is a discordia line is drawn and the intercepts are assigned a geological meaning, in the case of the wikipedia data ~50 Ma for the lower intercept and 461.17 ± 0.31 Ma. So that 220 or 230 Ma date is actually off by some 170 or 230 Ma, depending on whether the lower or upper intercept is more important.

From your quote:

and that many submarine basalts are not suitable for potassium-argon dating.

Why not “all submarine basalts are not suitable”? How can we distinguish the “good” from the “bad” before we run the date?

You say,

This is why they don’t use rocks that have xenocrysts in them.

But note the two-step above with phenocrysts.

You say,

What’s wrong with the studies that have already been done?

They’re not blinded, and I don’t know that all results have been reported.

Once again, if it is a field wide conspiracy of throwing out dates people don’t like then it is a simple matter of measuring those same rocks. Accusing scientists of fudging their data requires some actual evidence.

Again, you are missing the concerning thought process. The scientists don’t set out to fudge their data. It is just that they “know” the date they are supposed to get, and discordant data are attributed to some flaw in the sample and are possibly viewed as not worth reporting (positive results in any field are easier to publish than negative ones, and both are easier to publish than chaotic ones). You don’t have to invoke a grand conspiracy.

Again, maybe I’m barking up the wrong tree. But if so, it should be easy to prove.

RonSewell (C98),

The Existence of Carbon-14 in Very Old Fossil Material

… beyond that we are at an impasse at present.

I would agree that we don’t have “proof”, although there are other considerations that I will outline in the thread on radiocarbon in coal (again, if I am permitted).

But there are experiments that can help to further differentiate between the 2 major possibilities. And I plan to help get them done.

Errors in the Calibration Curve in the Historical Era

… For one, the earliest specific date which seems to enjoy universal recognition seems to be 690 BC with Sennacherib’s engagement with Hezekiah and Taharqa.

You may know that the argument under this heading lead to an article which is referenced near the end of C46, and therefore will not be repeated here (the computer tries to discourage multiple links to the same address in one thread). I just found out this last week that there is allegedly a similar problem in Jerusalem, although I do not know enough details yet (but am eagerly trying to find out). Do you have any actual radiocarbon data for the Sennacherib/Hezekiah/Taharqa connection, with a reference? It could have a bearing on our other data.

Zero missing rings over a millennium serves to validate confidence in the tree ring chronologies, and I am unable to find a creationist response.

My personal response is that this is what I expected. The Carbon-14 calibration curve has been validated IMO back to about 336 BC. So consilience at AD 744 would be expected in the theory I presently find most attractive.

Given that you do not seem to be a fan of speeded up decay, and that the tree ring / 14C conscilience is well supported, it appears to me that of the options you lay out in the article, that an ancient flood, constant decay model is the only one consistent with this scope of evidence.

I’m not so sure we can close the books on this question (partly because of the Nineveh bones apparent success), but you could be right. If I find enough data that supports the ancient flood, constant decay theory against the others, I will agree with that theory.